Technical Guide

Haynes 556: High-Temperature Sulfidation & Corrosion Resistance

UNS R30556 / W.Nr. 2.4839 — Iron-nickel-chromium-cobalt superalloy engineered for severe sulfidizing, carburizing, and oxidizing environments from 700°C to 1095°C.

Haynes 556 alloy material - Shanghai Hangbo Alloy
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Overview

Haynes 556 (UNS R30556 / W.Nr. 2.4839) is an iron-nickel-chromium-cobalt superalloy developed by Haynes International for demanding high-temperature environments where conventional stainless steels and even many nickel alloys fail prematurely. The alloy combines effective resistance to sulfidation, carburization, and chlorine-bearing oxidation with good elevated-temperature strength and excellent fabricability. Its balanced chemistry makes it one of the most cost-effective solutions for mixed-corrosion service between 700°C and 1095°C.

The defining metallurgical feature of Haynes 556 is its high chromium and cobalt content, supplemented by molybdenum, tungsten, nitrogen, and a rare-earth lanthanum addition. Chromium provides the primary oxidation and sulfidation resistance; cobalt improves sulfidation resistance and high-temperature strength; molybdenum and tungsten contribute solid-solution strengthening and resistance to reducing environments; nitrogen boosts creep strength; and lanthanum improves oxide-scale adhesion, reducing spallation during thermal cycling.

Unlike precipitation-hardenable superalloys such as Inconel 718 or Waspaloy, Haynes 556 is strengthened primarily by solid-solution mechanisms and nitrogen interstitial strengthening. This gives it excellent thermal stability and weldability without the risk of strain-age cracking. The alloy can be readily formed, welded, and machined using procedures similar to other Fe-Ni-Cr-Co alloys, making it attractive for complex fabrications such as waste-heat boiler tube bundles, furnace fixtures, and petrochemical reactor internals.

At Hangbo Alloy Group, Haynes 556 is supplied in plates, sheets, bars, seamless tubes, welded tubes, and welding wire per ASTM, ASME, AMS, and DIN/EN specifications. We support waste-to-energy plant operators, petrochemical refineries, cement and lime producers, and industrial furnace manufacturers with mill-direct supply, full certification, and custom cutting and machining services.

Quick Specifications

R30556
2.4839
8.23 g/cm³
1330 – 1415 °C
745 MPa (108 ksi)
455 MPa (66 ksi)
1095 °C (2000 °F)
∼40%

Chemical Composition (UNS R30556)

The chemistry of Haynes 556 is carefully balanced to provide both high-temperature corrosion resistance and practical mechanical properties. The high chromium and cobalt levels are the foundation of its sulfidation resistance, while nitrogen and the refractory metals molybdenum and tungsten provide solid-solution strengthening for elevated-temperature service. Lanthanum is added in trace amounts to improve the adherence of the protective oxide scale during thermal cycling.

ElementMin %Max %
Iron (Fe)BalanceBalance
Chromium (Cr)21.023.0
Nickel (Ni)19.022.5
Cobalt (Co)16.021.0
Molybdenum (Mo)2.54.0
Tungsten (W)2.03.5
Niobium (Nb)0.501.00
Tantalum (Ta)0.301.25
Nitrogen (N)0.100.30
Carbon (C)0.050.15
Manganese (Mn)2.00
Silicon (Si)0.75
Aluminum (Al)0.50
Lanthanum (La)0.0050.10
Phosphorus (P)0.040
Sulfur (S)0.015

Physical Properties

Haynes 556 has a face-centered cubic (FCC) austenitic structure in all standard supply conditions. Its physical properties are comparable to other Fe-Ni-Cr-Co high-temperature alloys, facilitating design calculations and welding to similar base metals. The alloy is essentially non-magnetic in the annealed condition.

PropertyValueUnit
Density8.23g/cm³
Melting Range1330 – 1415°C
Specific Heat (20°C)440J/kg·K
Thermal Conductivity (20°C)11.5W/m·K
Electrical Resistivity (20°C)1.20μΩ·m
Modulus of Elasticity (20°C)205GPa
Mean CTE (20–100°C)12.5μm/m·°C
Mean CTE (20–600°C)14.8μm/m·°C
Magnetic Permeability1.003(non-magnetic)

Mechanical Properties at Room Temperature

Haynes 556 is supplied in the solution-annealed condition, typically heat treated in the 1100–1175°C range followed by rapid cooling. The alloy exhibits a good combination of strength and ductility, with elongation around 40% that allows bending, spinning, and moderate cold forming. The values below are representative for annealed plate, sheet, and bar products.

PropertyAnnealed Value
Tensile Strength745 MPa (108 ksi)
Yield Strength (0.2% offset)455 MPa (66 ksi)
Elongation in 2 inches40%
Reduction of Area55%
Hardness90 HRB
Charpy V-notch Impact (RT)100 J min

High-Temperature Performance & Sulfidation Resistance

Haynes 556 was specifically developed to resist the combined effects of high temperature and aggressive corrosive gases. Its performance in sulfidizing, carburizing, and chloridizing environments is superior to most austenitic stainless steels and many nickel-base alloys, while its cost is lower than premium cobalt-base or high-nickel corrosion alloys.

Sulfidation Resistance

Sulfidation is one of the most aggressive forms of high-temperature corrosion in refineries, waste incinerators, and coal-conversion plants. In H2S-bearing or sulfur-oxide-bearing atmospheres, chromium forms protective sulfide-oxide scales, while cobalt improves the thermodynamic stability and mechanical integrity of these scales. Laboratory and field data show that Haynes 556 can last 2–4 times longer than Inconel 625 and Alloy 800H in mixed oxidation-sulfidation environments, making it a preferred upgrade for superheater tubes, reformer tubes, and calciner components.

Carburization & Nitridation Resistance

The high chromium and nickel content of Haynes 556 provides good resistance to carbon ingress in carburizing atmospheres such as those found in ethylene pyrolysis, direct reduction iron (DRI) processes, and carbon regeneration units. The alloy also resists nitridation in ammonia-rich or combustion exhaust environments better than many stainless steels, although Alloy 602CA or RA330 may be preferred for the most extreme carburizing or nitridizing conditions.

High-Temperature Strength

Thanks to nitrogen and refractory-metal solid-solution strengthening, Haynes 556 retains useful creep and rupture strength above 870°C. While it is not as strong as precipitation-hardened alloys such as Waspaloy or Inconel 718 at intermediate temperatures, it offers a better combination of strength and corrosion resistance than solid-solution alloys such as Alloy 800H or Inconel 625 in sulfidizing service.

Temperature (°C)Tensile Strength (MPa)Yield Strength (MPa)Elongation (%)
20 (Room)74545540
53862031045
76041522050
87129017055
98218011060
10931006570

Applications

Haynes 556 is selected wherever high-temperature strength must be combined with resistance to sulfidation, carburization, or chlorine-bearing oxidation. Its field-proven performance has made it a standard material in several demanding industries.

  • Waste Incineration: Boiler tubes, superheater tubes, water-wall panels, and economizers in municipal solid-waste and hazardous-waste incinerators. Chlorine and sulfur in the flue gas attack stainless steels rapidly; Haynes 556 provides dramatically longer tube life.
  • Petrochemical & Refining: Components exposed to high-sulfur feedstocks, including reformer tubes, transfer lines, calciners, and catalyst regenerators. The alloy resists sulfidation and carburization in hydrogen-hydrocarbon mixtures.
  • Chemical Processing: Rotary calciners, carbon regenerators, and high-temperature reaction vessels handling sulfur- and chlorine-containing process streams.
  • Industrial Heating: Furnace rolls, radiant tubes, heat-treatment fixtures, and radiant burner tubes in carburizing and carbonitriding furnaces.
  • Coal Gasification & Power: Heat exchangers, syngas coolers, and combustion hardware in integrated gasification combined-cycle (IGCC) plants.
  • Hot-Dip Galvanizing: Hardware such as sink rolls, stabilizer rolls, and bearings exposed to molten zinc at 450–470°C, where the alloy resists liquid-metal attack and oxidation.
  • Aerospace: High-temperature fasteners, combustor components, and afterburner parts where oxidation and sulfidation resistance are required.

Available Product Forms

Hangbo Alloy Group supplies Haynes 556 in the full range of product forms required by waste-to-energy, petrochemical, and industrial heating customers. Material is supplied in the solution-annealed condition with EN 10204 3.1 mill test certificates and full traceability. Custom cutting, machining, and export packaging are available.

  • Round Bars: ASTM B572, diameters 8 mm to 250 mm, hot-rolled, forged, or cold-drawn, for fasteners, shafts, and machined components.
  • Plates & Sheets: ASTM B435, thickness 0.5 mm to 50 mm, for boiler tube panels, heat shields, and pressure vessel shells.
  • Seamless Tubes & Pipes: ASTM B622, OD 6 mm to 219 mm, for superheater tubes, heat exchangers, and process piping.
  • Welded Tubes & Pipes: ASTM B619/B626, for larger-diameter ducting and economizer applications.
  • Fittings & Forgings: ASTM B366 and custom forgings for elbows, tees, header boxes, and furnace roll bodies.
  • Welding Wire: ERNiCrCoMo-1 / AMS 5830, for fabrication and repair of Haynes 556 components.

Welding & Fabrication

Haynes 556 is readily welded by gas tungsten arc welding (GTAW/TIG), gas metal arc welding (GMAW/MIG), and shielded metal arc welding (SMAW). Its austenitic structure and moderate work-hardening rate make it more fabricable than many high-nickel or cobalt-base alloys.

  • No preheat required for most section thicknesses. Interpass temperature should be kept below 150°C to minimize oxide formation.
  • Matching filler metal such as ERNiCrCoMo-1 or Haynes 556 bare wire is recommended for joining the alloy to itself and for overlays where identical corrosion resistance is needed.
  • Dissimilar welds to austenitic stainless steels or nickel alloys can be made with ERNiCr-3 (Inconel 82) or ERNiCrMo-3 (Inconel 625) filler, depending on the service environment.
  • Post-weld heat treatment is generally not required for corrosion resistance. Solution annealing at 1100–1175°C may be performed to restore ductility after severe cold forming or to relieve residual stresses in critical fabrications.
  • Hot forming is performed at 950–1200°C. The alloy has good hot ductility and can be bent, forged, and rolled using conventional equipment.
  • Machining requires rigid setups, carbide or ceramic tools, moderate speeds, and generous coolant, similar to other austenitic high-temperature alloys.

Related Standards

StandardDescription
ASTM B435Plate, Sheet, and Strip
ASTM B572Bar, Rod, and Wire
ASTM B622Seamless Pipe and Tube
ASTM B619 / B775Welded Pipe
ASTM B626 / B751Welded Tube
ASTM B366Fittings
ASTM B472Billet and Bar for Reforging
AMS 5531Sheet, Strip, and Plate
AMS 5831Bar, Rod, Forging, and Wire
AMS 5830Welding Wire
ASME SB-435 / SB-572 / SB-622Boiler and Pressure Vessel Code
DIN/EN W.Nr. 2.4839German/European Material Designation

Buy Haynes 556 from Hangbo Alloy Group

Shanghai Hangbo Alloy Group is a professional manufacturer and global supplier of Haynes 556 (UNS R30556 / W.Nr. 2.4839). We provide plates, sheets, bars, seamless tubes, welded tubes, fittings, and welding wire with full material certification per ASTM, ASME, AMS, and EN standards. Mill-direct pricing, ISO 9001:2015 quality system, and fast delivery to 50+ countries worldwide.

Email: hangbo@nickel-alloy.com  |  Phone: +86-136-1165-6360  |  WhatsApp: +86 13611656360
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Frequently Asked Questions (FAQ)

1. What is Haynes 556 alloy?

Haynes 556 (UNS R30556 / W.Nr. 2.4839) is an iron-nickel-chromium-cobalt superalloy designed for high-temperature service in severely corrosive environments. It combines excellent resistance to sulfidation, carburization, and oxidation with good high-temperature strength and fabricability.

2. What is the chemical composition of Haynes 556?

Nominal composition: Fe balance (~31%), Cr 21.0–23.0%, Ni 19.0–22.5%, Co 16.0–21.0%, Mo 2.5–4.0%, W 2.0–3.5%, Nb 0.50–1.00%, Ta 0.30–1.25%, N 0.10–0.30%, C 0.05–0.15%, plus controlled Mn, Si, Al, La, S, and P. The high Cr-Co-Mo-W combination and rare-earth lanthanum provide its unique corrosion resistance.

3. What is the density and melting range of Haynes 556?

Haynes 556 has a density of approximately 8.23 g/cm³ (0.297 lb/in³) and a melting range of 1330–1415°C (2425–2575°F).

4. What are the mechanical properties of Haynes 556 at room temperature?

Typical annealed properties: tensile strength ~745 MPa (108 ksi), yield strength ~455 MPa (66 ksi), elongation ~40%, hardness ~90 HRB. The alloy retains useful strength and creep resistance from 700°C up to 1095°C.

5. What standards apply to Haynes 556?

Key standards: ASTM B435 (plate/sheet/strip), ASTM B572 (bar/rod), ASTM B622 (seamless pipe/tube), ASTM B619/B775 (welded pipe), ASTM B626/B751 (welded tube), ASTM B366 (fittings), AMS 5531/5831/5830, and W.Nr. 2.4839.

6. How does Haynes 556 resist sulfidation?

Haynes 556 resists sulfidation through its high chromium, cobalt, and molybdenum content, which form stable protective sulfide-oxide scales. In mixed oxidation-sulfidation environments, it typically lasts 2–4 times longer than Inconel 625 and Alloy 800H.

7. What is the maximum service temperature of Haynes 556?

Haynes 556 is designed for continuous service from 700°C up to 1095°C (2000°F). Under low stress and clean oxidizing conditions, short-term exposure to 1150°C is possible without catastrophic scale spallation.

8. What are typical applications of Haynes 556?

Primary applications: waste incineration boiler and superheater tubes, rotary calciners, petrochemical reformer tubes, catalyst regenerators, industrial furnace fixtures, coal gasification heat exchangers, hot-dip galvanizing hardware, and gas turbine fasteners.

9. Can Haynes 556 be welded and fabricated?

Yes, Haynes 556 has excellent weldability using GTAW, GMAW, and SMAW processes. Matching filler metals such as ERNiCrCoMo-1 or Haynes 556 bare wire are preferred. No preheat is required, and post-weld heat treatment is generally not necessary for corrosion resistance.

10. What product forms are available for Haynes 556?

Hangbo Alloy Group supplies Haynes 556 in round bars, plates/sheets/strips, seamless tubes/pipes, welded tubes/pipes, fittings, welding wire, and custom forgings. All products are delivered with EN 10204 3.1 mill test certificates and full traceability.

11. How does Haynes 556 compare to Inconel 625 and Alloy 800H?

In sulfidizing and carburizing environments, Haynes 556 outperforms both Inconel 625 and Alloy 800H due to its higher Cr-Co content and rare-earth-modified oxide scale. Its creep strength above 870°C is also superior. For strongly reducing acids, Hastelloy C-276 is preferred; for pure oxidation above 1100°C, Alloy 602CA or RA330 may be better choices.

12. What is the price and lead time for Haynes 556?

Haynes 556 is a premium specialty alloy. Typical mill-direct pricing ranges from $25–45/kg for bars, $35–60/kg for plates, and $50–90/kg for seamless tubes, depending on size and quantity. Lead times are typically 8–12 weeks for custom mill orders; Hangbo Alloy maintains strategic inventory of common sizes for 2–4 week delivery. MOQ is generally 50 kg for stock sizes and 200–500 kg for custom sizes.

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