Technical Guide

Inconel 693: Metal Dusting Resistance & High-Temperature Alloy Properties

UNS N06693 / W.Nr. 2.4646 — Nickel-chromium-aluminum superalloy engineered for extreme resistance to metal dusting, carburization, and high-temperature oxidation in syngas, ammonia, and petrochemical service.

Inconel 693 alloy material - Shanghai Hangbo Alloy
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Overview

Inconel 693 (UNS N06693 / W.Nr. 2.4646) is a nickel-chromium-aluminum superalloy specifically developed by Special Metals to combat metal dusting, a catastrophic form of high-temperature corrosion that occurs in carbon-supersaturated atmospheres at temperatures between approximately 400°C and 800°C. The alloy achieves its remarkable resistance through an exceptionally high aluminum content (3.0–3.5% typical) that promotes the formation of a continuous, self-healing aluminum oxide (Al2O3) layer on the metal surface. This alumina scale is essentially impermeable to carbon atoms, blocking the carbon ingress that drives the metal dusting mechanism.

Metal dusting is a leading cause of unscheduled downtime in syngas coolers, ammonia reformers, methanol synthesis loops, and direct reduction iron (DRI) process equipment. Conventional alloys such as Incoloy 800H, 304H stainless, or HK40 cast tubes can experience metal loss rates of several millimeters per year in such environments, sometimes perforating tube walls within months. Inconel 693 was engineered to provide decades of service in these conditions, dramatically extending inspection intervals and reducing total cost of ownership.

Beyond its anti-dusting capability, Inconel 693 offers solid high-temperature oxidation resistance up to approximately 1100°C in air, comparable to many Fe-Ni-Cr alloys. The 30% chromium level provides adequate sulfidation resistance for low-to-moderate sulfur environments, while the high aluminum improves carburization resistance in CO-rich and hydrocarbon atmospheres. The alloy is supplied in the solution-annealed condition and is non-age-hardenable, with strength derived from solid-solution strengthening and the fine grain size maintained by aluminum and niobium additions.

At Hangbo Alloy Group, we supply Inconel 693 round bars, seamless tubes, plates, sheets, and welding wire to syngas technology licensors, ammonia plant operators, methanol producers, and petrochemical engineering contractors worldwide. Our mill-direct supply chain ensures full traceability, EN 10204 3.1 certification, and competitive delivery to 50+ countries.

Quick Specifications

N06693
2.4646
7.77 g/cm³
1310 – 1370 °C
700 MPa (102 ksi)
340 MPa (49 ksi)
1100 °C (2010 °F)
Metal Dusting Resistance

Chemical Composition (ASTM B166 / UNS N06693)

The defining feature of Inconel 693's chemistry is its high aluminum content. While conventional austenitic nickel and Fe-Ni-Cr alloys contain 0.1–0.5% aluminum to improve oxidation resistance, Inconel 693 contains 2.5–4.0% aluminum — sufficient to form a continuous, protective Al2O3 scale instead of the more common Cr2O3 scale. This single compositional change is what makes the alloy uniquely resistant to metal dusting. Niobium (0.5–2.5%) contributes to grain refinement and creep strength, while chromium (27–31%) ensures adequate sulfidation resistance and supports the alumina scale formation in transitional atmospheres.

ElementMin %Max %
Nickel + Cobalt (Ni+Co)58.063.0
Chromium (Cr)27.031.0
Aluminum (Al)2.504.00
Iron (Fe)3.05.0
Niobium (Nb)0.502.50
Manganese (Mn)1.0
Titanium (Ti)1.0
Copper (Cu)0.50
Carbon (C)0.15
Silicon (Si)0.50
Sulfur (S)0.010
Phosphorus (P)0.020

Physical Properties

Inconel 693 has a face-centered cubic (FCC) austenitic matrix in all standard supply conditions. Its physical constants reflect the lower density typical of high-aluminum nickel alloys and the moderate thermal conductivity expected for austenitic Ni-Cr compositions. These values are used in thermal stress, heat transfer, and pressure vessel design calculations per ASME and EN standards.

PropertyValueUnit
Density7.77g/cm³
Melting Range1310 – 1370°C
Specific Heat (20°C)450J/kg·K
Thermal Conductivity (20°C)11.7W/m·K
Electrical Resistivity (20°C)1.18μΩ·m
Modulus of Elasticity (20°C)196GPa
Mean CTE (20–100°C)12.2μm/m·°C
Mean CTE (20–600°C)14.4μm/m·°C
Magnetic Permeability1.001(non-magnetic)

Mechanical Properties at Room Temperature

Inconel 693 is supplied in the solution-annealed condition (typically 1100–1150°C followed by rapid cooling) and is not age-hardenable. Strength is derived from solid-solution strengthening by chromium and niobium, plus fine grain size stabilization by aluminum and niobium. The values below represent typical room-temperature tensile properties for annealed bar, plate, and tube products per ASTM B166/B168.

PropertyAnnealed Value
Tensile Strength700 MPa (102 ksi) min
Yield Strength (0.2% offset)340 MPa (49 ksi) min
Elongation in 2 inches35% min
Reduction of Area50% min
Hardness85 HRB max (180 HB)
Charpy V-notch Impact (RT)120 J min

The high ductility (35% elongation) is a significant advantage for fabricators: Inconel 693 can be cold-bent, hot-bent, and formed into complex tube bends, header boxes, and pressure vessel heads without cracking. This is in contrast to high-chromium cast alloys such as HK40 or HP40, which are limited to straight tubes and require expensive welding procedures for branch connections.

High-Temperature Mechanical Properties

Although Inconel 693 is not a high-strength superalloy in the Waspaloy or Inconel 718 sense, it retains useful strength and creep resistance at temperatures up to about 800°C. Its primary use temperature range is 400–800°C (the metal dusting window) where its combination of strength, ductility, and protective scale is unmatched. For short-term exposure, the alloy can be used up to 1100°C with acceptable oxidation behavior.

Temperature (°C)Tensile Strength (MPa)Yield Strength (MPa)Elongation (%)
20 (Room)72036042
20068032040
40062028042
60058026045
70051024048
80038021055
90024017065
100014011075

For comparison, the 100,000-hour rupture stress at 700°C is approximately 30–40 MPa, and at 800°C approximately 15–20 MPa. These values are adequate for headers, transfer lines, and pressure vessel shells but are not sufficient for highly stressed rotating components.

Metal Dusting Resistance

Metal dusting is a form of catastrophic high-temperature corrosion that occurs when alloys are exposed to strongly carburizing atmospheres (high carbon activity, low oxygen partial pressure) at temperatures typically between 400°C and 800°C. The mechanism involves the decomposition of CO or hydrocarbons on the metal surface, dissolution of carbon into the alloy, and subsequent precipitation of graphite particles that disrupt the metal matrix, causing it to disintegrate into a powder of metal particles, graphite, and oxides. Affected components can lose several millimeters of wall thickness per year and fail suddenly through perforation.

Conventional austenitic stainless steels and Fe-Ni-Cr alloys rely on a Cr2O3 oxide scale for protection. Unfortunately, chromia is permeable to carbon at elevated temperatures, and in CO-rich syngas, the chromia layer cannot prevent carbon from reaching the metal below. Once carbon saturates the underlying metal, metal dusting initiates and proceeds rapidly. The traditional mitigation strategy — increasing chromium content — only delays the attack.

Inconel 693 solves this problem by switching the protective oxide from chromia to alumina. The 3% aluminum content is sufficient to form a continuous Al2O3 layer on the metal surface, which is far more thermodynamically stable and essentially impermeable to carbon. Alumina does not catalyze the Boudouard reaction (2CO → CO2 + C), so the carbon deposition step that initiates metal dusting is suppressed at the surface.

Comparative Metal Dusting Test Results

The table below shows typical mass loss and pit depth data from a 500-hour laboratory test in 50% CO / 50% H2 / 1% H2O at 650°C (severe metal dusting conditions):

AlloyMass Loss (mg/cm²)Max Pit Depth (μm)Visual Rating
Inconel 693< 0.50 – 5No attack
Alloy 602CA2 – 520 – 40Light pitting
Incoloy 800H25 – 50200 – 400Severe dusting
Type 304H SS60 – 100500 – 800Catastrophic failure
HK40 (25Cr/20Ni cast)15 – 35150 – 300Severe dusting

Under identical test conditions, Inconel 693 is essentially unattacked while 304H stainless and Incoloy 800H suffer catastrophic metal loss. In real plant service, this translates to inspection intervals measured in years for Inconel 693 versus weeks or months for unprotected alloys.

Carburization Resistance

Beyond metal dusting, Inconel 693 also resists bulk carburization in high-carbon-activity environments. The same Al2O3 layer that blocks dusting also blocks the slower carbon diffusion process responsible for carburization. Carburized layers in 800H after 10,000 hours at 700°C can reach depths of 1–3 mm, while Inconel 693 typically shows carbon ingress of less than 0.05 mm — essentially background noise. This dramatically reduces the risk of brittle fracture in reformer outlet piping and transfer line systems.

Applications

Inconel 693 is selected wherever metal dusting or severe carburization threatens the integrity of process equipment. Its primary applications are concentrated in syngas, ammonia, methanol, and direct reduction iron service, but it is increasingly specified in petrochemical and chemical processing where carbon activities are high.

  • Syngas Coolers and Heat Exchangers: Coal-to-chemicals, gasification, and partial oxidation plants where raw syngas (CO + H2 + CO2 + H2O) cools from 800–1200°C to 200–400°C. Tubes in the 400–700°C window are at extreme metal dusting risk; Inconel 693 has become the industry standard for these heat-exchanger bundles.
  • Ammonia Primary Reformer Outlet Piping: The transfer line between the reformer furnace and secondary reformer contains process gas with very high carbon activity. Inconel 693 transfer lines have demonstrated life exceeding 15 years in commercial service, while conventional 800H piping required replacement every 2–4 years.
  • Methanol Synthesis Reactor Internals: Inlet and outlet headers, catalyst basket supports, and internal piping exposed to syngas with carbon activity approaching 1. Inconel 693 eliminates the metal dusting failures historically common in methanol loop piping.
  • Direct Reduction Iron (DRI) Process Equipment: Reduction gas coolers, gas mixing tubes, and process gas piping where CO-rich atmospheres at 500–700°C attack conventional alloys.
  • Ethylene Pyrolysis Transfer Line Exchangers (TLE): While not a primary TLE alloy, Inconel 693 has been used in the secondary decoking gas piping and downstream pre-heat exchangers where carbon activities are very high.
  • Carburizing Furnace Fixtures: Baskets, trays, and fixtures in low-temperature (650–800°C) carburizing furnaces that would otherwise suffer metal dusting during cool-down cycles when CO-rich atmospheres contact the alloy.
  • Hydrogen Plant Reformer Outlet Systems: Replacement for 800H piping and headers that have failed by metal dusting in steam methane reforming (SMR) hydrogen plants.

Available Product Forms

Hangbo Alloy Group supplies Inconel 693 in the full range of product forms required by syngas plant designers and ammonia plant operators. All products are supplied in the solution-annealed condition and accompanied by EN 10204 3.1 mill test certificates with full traceability.

  • Seamless Tubes & Pipes: ASTM B167 / ASME SB-167, OD 10 mm to 168 mm (larger sizes available on request), wall thickness 1–15 mm. U-bent tubes, hairpin bends, and welded-and-re-drawn (WFD) tubes available for syngas cooler bundles.
  • Round Bars: ASTM B166, diameters 8 mm to 200 mm, hot-finished or cold-drawn, solution annealed. For header forging stock, flange blanks, and machined components.
  • Plates & Sheets: ASTM B168, thickness 1 mm to 30 mm, for vessel shells, transition pieces, and large structural fabrications.
  • Forged Fittings: Elbows, tees, reducers, and header boxes per ASME B16.9 or custom forging drawings, machined from forged billet with full ultrasonic examination.
  • Welding Wire: Matching filler metal for GTAW/GMAW welding of Inconel 693 components. Inquire for current availability and spool sizes.
  • Bimetallic Tubes: Inconel 693 clad over carbon steel or low-alloy steel base for cost-effective large-diameter reformer outlet piping where the inner surface is the critical corrosion zone.

Welding & Fabrication

Inconel 693 is readily welded using conventional gas tungsten arc welding (GTAW/TIG) and gas metal arc welding (GMAW/MIG) processes. Its high ductility and resistance to hot cracking make it significantly more weldable than high-chromium nickel alloys or iron-nickel-chromium alloys prone to weld sensitization.

Key welding considerations:

  • No preheat required — the alloy is fully austenitic and ductile at room temperature, eliminating cold-cracking concerns common in thick-section welds.
  • Matching filler metal such as ERNiCrAl-1 (ERNiCrFe-12 is also used with care on dilution) is preferred for joining Inconel 693 to itself. For dissimilar welds to other nickel alloys, ERNiCr-3 (Inconel 82) or ERNiCrMo-3 (Inconel 625) filler is commonly used.
  • Post-weld solution anneal at 1100–1150°C for 30–60 minutes followed by rapid cooling is recommended to dissolve any weld precipitates and restore the optimum aluminum distribution for protective scale formation in service.
  • Hot forming should be performed at 1000–1200°C. The alloy has good hot workability and can be bent, spun, and upset-forged using standard procedures.
  • Cold forming is feasible for sheet and strip; intermediate anneals at 1100°C may be required after severe deformation to restore ductility.
  • Machining is similar to other austenitic nickel alloys: use carbide tools, moderate cutting speeds, positive feed rates, and generous coolant. The alloy work-hardens moderately during machining.

Related Standards

StandardDescription
ASTM B166Nickel-Chromium-Iron Alloy Rod, Bar & Wire
ASTM B167Nickel-Chromium-Iron Alloy Seamless Pipe & Tube
ASTM B168Nickel-Chromium-Iron Alloy Plate, Sheet & Strip
ASTM B516Welded Nickel-Chromium-Iron Alloy Tubes
ASME SB-166 / SB-167 / SB-168Boiler and Pressure Vessel Code (Section II)
ASME Code Case 2680Use of N06693 in Pressure Vessels
DIN 17742German Standard for NiCrAl Alloy
EN 10095Heat-Resisting Steels and Nickel Alloys
VDTÜV 305German Pressure Vessel Approval (Material 2.4646)

Buy Inconel 693 from Hangbo Alloy Group

Shanghai Hangbo Alloy Group is a professional manufacturer and global supplier of Inconel 693 (UNS N06693 / W.Nr. 2.4646). We provide seamless tubes, plates, round bars, welding wire, and custom forgings with full material certification per ASTM, ASME, and EN standards. Mill-direct pricing, ISO 9001:2015 quality system, and fast delivery to 50+ countries worldwide.

Email: hangbo@nickel-alloy.com  |  Phone: +86-136-1165-6360  |  WhatsApp: +86 13611656360
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Frequently Asked Questions (FAQ)

1. What is the maximum service temperature of Inconel 693?

Inconel 693 is designed for continuous service up to approximately 700°C (1290°F) in strongly carburizing atmospheres where metal dusting is the dominant failure mode. The alloy retains its protective Al2O3 oxide scale up to about 1100°C in oxidizing environments, but its primary use is in the 450–700°C metal dusting range.

2. What is the density of Inconel 693?

Inconel 693 has a density of approximately 7.77 g/cm³ (0.281 lb/in³), which is lower than most nickel superalloys due to its high aluminum content (around 3.1%) and the absence of heavy molybdenum or tungsten additions.

3. What is the chemical composition of Inconel 693?

Nominal composition: Ni+Co 58–63%, Cr 27–31%, Al 2.5–4.0%, Fe 3.0–5.0%, Nb 0.5–2.5%, plus C ≤0.15%, Mn ≤1.0%, Ti ≤1.0%. The high aluminum (3.1% typical) forms a continuous Al2O3 oxide layer that is impermeable to carbon and provides exceptional metal dusting resistance.

4. What standards apply to Inconel 693?

Key standards: ASTM B166 (rod/bar/wire), ASTM B167 (seamless tube/pipe), ASTM B168 (plate/sheet/strip), ASTM B516 (welded tube), ASME Code Case 2680 (pressure vessels), DIN 17742, EN 10095, and VdTÜV 305. The alloy is also known commercially as Nicrofer 6030 or Alloy 693.

5. How does Inconel 693 resist metal dusting?

Inconel 693 resists metal dusting through its high aluminum content (3.1%), which forms a continuous, self-healing Al2O3 oxide layer on the surface. This aluminum oxide scale is highly impermeable to carbon atoms, preventing the carbon supersaturation and graphite nucleation that initiate metal dusting attack. In standard 500-hour tests at 650°C in CO-H2-H2O atmospheres, Inconel 693 shows essentially no metal dusting, while standard alloys like 800H or HK40 suffer severe attack.

6. What is the price range for Inconel 693 products?

Inconel 693 is a specialty alloy with limited global production. Typical mill-direct pricing: round bars $30–50/kg, seamless tubes $55–85/kg, plates $40–60/kg, welding wire $80–120/kg. Pricing depends on dimensions, quantity, and current market conditions. Contact Hangbo Alloy for quotation.

7. What product forms are available for Inconel 693?

Hangbo Alloy Group supplies Inconel 693 in: round bars (8–200mm diameter), seamless tubes/pipes (OD 10–168mm), plates/sheets (1–30mm), welding wire, and custom forgings. All products are delivered with material test certificates per EN 10204 3.1 and full traceability. Bimetallic tubes (Inconel 693 clad over carbon steel) are available for cost-effective reformer outlet piping.

8. Can Inconel 693 be welded?

Yes, Inconel 693 can be welded using GTAW (TIG) and GMAW (MIG) processes. Matching filler metal is typically ERNiCrAl-1 or ERNiCrFe-12 (with caution on dilution). Dissimilar welds to other nickel alloys commonly use ERNiCr-3 (Inconel 82) or ERNiCrMo-3 (Inconel 625). Post-weld solution annealing at 1100–1150°C is recommended to restore the optimal aluminum oxide formation in the weld zone.

9. What are the typical applications of Inconel 693?

Primary applications: syngas coolers and heat exchangers in coal-to-chemicals and gasification plants, ammonia primary reformer outlet piping and headers, methanol synthesis reactor internals, ethylene pyrolysis transfer line exchangers, direct reduction iron (DRI) process equipment, and any environment where carbon activity exceeds 1 and temperatures are between 400–800°C.

10. How does Inconel 693 compare to Alloy 800H for metal dusting service?

Inconel 693 is dramatically superior to Alloy 800H in metal dusting environments. While 800H is not designed for metal dusting and typically shows severe pitting and metal loss within weeks in CO-rich syngas at 600°C, Inconel 693 remains essentially unattacked for thousands of hours. The performance difference is primarily due to the Al2O3 vs Cr2O3 oxide chemistry: alumina is far more impermeable to carbon than chromia. Inconel 693 is the preferred upgrade for plant operators experiencing metal dusting failures.

11. Does Inconel 693 resist sulfidation?

Inconel 693 has moderate sulfidation resistance due to its 30% chromium content, but it is not optimized for high-sulfur environments. In atmospheres containing H2S above 0.5% or sulfur partial pressures above 10 Pa, Inconel 693 may experience accelerated attack. For high-sulfur service, Alloy 602CA or specialized nickel-cobalt alloys may be more suitable.

12. What is the lead time and MOQ for Inconel 693 products?

Standard Inconel 693 mill products have typical lead times of 8–14 weeks due to limited global production. Hangbo Alloy maintains strategic inventory of common bar and tube sizes with 2–4 week delivery for stocked items. MOQ is generally 50 kg for stock products and 200–500 kg for custom sizes. Mill test certificates, PMI verification, and third-party inspection (SGS/BV/TUV) are available on request.

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